PO86 


Poster Session


Shear thinning and thickening behaviors of hollow carbon nanoparticles in Newtonian fluids


October 23, 2019 (Wednesday) 6:30


Poster Session / Ballroom C on 4th floor

(Click on name to view author profile)

  1. Kiany, Parvin (Amirkabir University of Technology, Polymer Engineering)
  2. Goharpey, Fatemeh (Amirkabir University of Technology, Polymer Engineering)
  3. Foudazi, Reza (New Mexico State University, Department of Chemical and Materials Engineering)

(in printed abstract book)
Parvin Kiany1, Fatemeh Goharpey1, and Reza Foudazi2
1Polymer Engineering, Amirkabir University of Technology, Tehran, Iran; 2Department of Chemical and Materials Engineering, New Mexico State University, Las Cruces, NM 88003


Goharpey, Fatemeh


We investigated the rheological properties of hollow carbon spheres (HCSs) suspended in polyethylene glycol (PEG-400) at different volume fractions. The viscosity increases and the shear thinning behavior intensifies with volume fraction. At 12 vol% of HCSs, with increasing the shear rate, shear thinning is followed by shear thickening and a secondary shear thinning. This behavior can be attributed to the aggregation of HCSs due to their attractive surface (their zeta potential is lower than 30 mV). Based on Krieger-Dougherty equation, the maximum packing volume fraction of HCSs is about 0.53. Under weak shear, negative normal stress differences are observed, which can be attributed to the alignment of aggregates. When hybrids of bowl-like and spherical particles are used, the shear thickening behavior is diminished in the studied experimental shear rate range.