Paper Number
SF20
Session
Self-assembly and Flow-induced Systems/Gels
Title
Study of diffusion effects in shear banding micellar solutions
Presentation Date and Time
October 8, 2014 (Wednesday) 11:40
Track / Room
Track 5 / Washington B
Authors
- Germann, Natalie (Technical University of Munich Weihenstephan, Center of Life and Food Sciences)
- Beris, Antony N. (University of Delaware, Chemical and Biomolecular Engineering)
- Cook, L.Pamela (University of Delaware, Department of Mathematical Sciences)
Author and Affiliation Lines
Natalie Germann1, Antony N. Beris2, and L.Pamela Cook3
1Center of Life and Food Sciences, Technical University of Munich Weihenstephan, Freising 85354, Germany; 2Chemical and Biomolecular Engineering, University of Delaware, Newark, DE 19716; 3Department of Mathematical Sciences, University of Delaware, Newark, DE 19716
Speaker / Presenter
Beris, Antony N.
Text of Abstract
This theoretical modeling work follows in continuation to our modeling efforts on the shear banding behavior of wormlike micellar solutions. By employing an extension to the nonequilibrium treatment of chemical reaction kinetics for media with an internal structure, we described the dynamic breakage and recombination processes of the micelles (1). Standard Fickian and stress-induced diffusion was added in a thermodynamically consistent fashion (2). In this talk, we will address the influence of the various diffusion effects to the solution of the problem with typical results presented and limiting cases analyzed. Of particular emphasis will be the stress-induced diffusion as it does appear to affect the smoothness of the solution indicating it as a key parameter to spectral approximations. The connection to the physics will be made and typical applications where the diffusion effects are important will be discussed.
References
(1) N. Germann, L. P. Cook, and A. N. Beris. Nonequilibrium thermodynamic modeling of the structure and rheology of concentrated micellar solutions, J. Non-Newt. Fluid Mech., (196):51-57, 2013.
(2) N. Germann, L. P. Cook, and A. N. Beris. Investigation of the inhomogeneous shear flow of a wormlike micellar solution using a thermodynamically consistent model, J. Non-Newt. Fluid Mech., (207):21-31, 2014.